Product ID:CHARGE,PROPELLING,M67 ASSEMBLY
MSDS Date:08/21/1991
FSC:1315
NIIN:01-237-9775
MSDS Number: BPRQK

ICI AMERICAS INC FILMS DIV

NEW MURPHY RD AND CONCORD PIKE
WILMINGTON, DE 19897
US

Emergency Phone: 800-327-8633 (MEDICAL)

Info Phone: 302-886-3000 (TECHNICAL)

Cage: 70657

ICI AMERICAS INC FILMS DIV

WILMINGTON, DE 19897 US

Cage: 70657

DINITROTOLUENE (SARA III)

CAS: 121-14-2

RTECS: XT1575000

Fraction By Weight: 10%

OSHA PEL 1.5 MG/M3 SKIN

ACGIH TLV: NOT KNOWN

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

DIBUTYL PHTHALATE (SARA III)

CAS: 84-74-2

RTECS: TI0875000

Fraction By Weight: 5%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

DIPHENYLAMINE

CAS: 122-39-4

RTECS: JJ7800000

Fraction By Weight: 1%

OSHA PEL 10 MG/M3

ACGIH TLV: 10 MG/M3

LEAD CARBONATE.ACGIH TLV IS FOR INORGANIC LEAD DUSTS AND

CAS: 598-63-0

RTECS: OF9275000

Fraction By Weight: 1%

OSHA PEL NOT KNOWN

ACGIH TLV: 0.15 MG(PB)/M3

NITROCELLULOSE

CAS: 9004-70-0

RTECS: QW0970000

Fraction By Weight: 85%

OSHA PEL NOT KNOWN

ACGIH TLV: NOT KNOWN

POTASSIUM SULFATE

CAS: 7778-80-5

RTECS: TT5900000

Fraction By Weight: 1%

OSHA PEL NOT KNOWN

ACGIH TLV: NOT KNOWN

LD50 LC50 Mixture:LD50 RAT ORAL >5 G/KG PROPELLENT (EST).
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF
OVEREXPOSURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:TOXICITY INFO NOT AVAIL.PROPELLANT IN CLOTH BAG
HANDLED IAW GOOD INDUS HYG MAY NOT PRESENT HEALTH
HAZARD.SKIN:RPTD/PRLNGD CONTACT W/ PROPELLANT MAY
IRRITATE.ABSORPTION/INGEST/INHAL OF DINITROTOLUENE M AY CAUSE
FORMATION OF METHEMOGLOBINEMIAW/ CYANOSIS,NAUS,CONFUSION.SINGLE
DOSE INGESTED IS PRACTICALLY NONTOXIC.
Medical Cond Aggravated by Exposure:NOT KNOWN

First Aid:OPEN BAG W/ SIGNIFICANT EXPOS:EYES:FLUSH W/ H*2O.REMOVE
CONTACT LENSES.CONTINUE FLUSHING FOR AT LEAST 15 MIN.IF SYMPTOMS
DEVELOP,GET MED HELP. SKIN:WASH SKIN/HAIR/NAILS W/ LOTS OF SOAP &
H*2O.GET MED ATTN. INGEST:DRINK 1-2 GLASSES OF H*2O.SEE MED
PERS.GIVE NOTHING BY MOUTH IF UNCON. INHAL:MOVE TO FRESH AIR.IF NOT
BRTHG,GIVE ARTF RESP,PREF MOUTH-TO-MOUTH.IF BRTHG LABORED:GIVE
O*2.CONSULT MED PERS.

Extinguishing Media:DELUGE WITH WATER.ALL MATERIAL WILL PROBABLY BE
CONSUMED BEFORE FIRE EXTINGUISHED UNLESS USE LOTS OF WATER VERY
QUICKLY.
Fire Fighting Procedures:EVACUATE THE AREA.
Unusual Fire/Explosion Hazard:EASILY IGNITED,HIGHLY COMBUSTIBLE
EXPLOSIVE.

Spill Release Procedures:OPEN BAG:ELIMINATE IGNITION SOURCES.VENTILATE
AREA.WEAR SKIN & RESP PROTECTION.CLEAN UP IMMEDIATELY USING SOFT
BRISTLED BRUSH & CONDUCTIVE RUBBER OR PLASTIC SHOVEL.USE EXTREME
CAUTION;MATL IS SENSITIV E TO FRICTION,IMPACT & ELECTROSTATIC
DISCHARGE.
Neutralizing Agent:NOT KNOWN

Handling and Storage Precautions:FOLLOW ARMY REGS FOR HNDLG &
STORAGE.SENSITIVE TO FRICTION,IMPACT,ELECTROSTATIC
DISCHARGE.CONTROL OF EXPOSURE TO SUFF.
Other Precautions:PREVENT SKIN CONTACT W/ BAG CONTENTS.AVOID BREATHING
DUST.OPEN VAPOR BAGS IN WELL VENT AREA,ALLOW VAPORS TO ESCAPE
BEFORE FURTHER HANDLING.MINIMIZE EXPOS W/ GOOD HYGIENE PRACTICES.

Respiratory Protection:MSHA-NIOSH APPROVED POSITIVE PRESSURE
AIR-SUPPLIED RESPIRATOR PROVIDES THE BEST PROTECTION.
Ventilation:USE LOCAL EXHAUST TO KEEP EXPOSURES TO A MINIMUM.
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:COVERALLS AND APRON.EYEWASH FACILITIES AS
NEEDED.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING DAILY &
DECONTAMINATE FOOTWEAR BEFORE REUSE.SHOWER THOROUGHLY AT END OF
WORK SHIFT.(SEE SUP)
Supplemental Safety and Health
PART NUMBER:9205472.SPECIFIC GRAVITY:1.5 (WATER=1) FOR PROPELLENT
M1.HYGIENE PRACT:THOROUGHLY WASH HANDS & FACE WITH SOAP & WATER
BEFORE EATING,DRINKING OR SMOKING.EATING,DRINKING OR SMOKING SHOULD
NO T BE ALLOWED IN HANDLING AREAS.

Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN
Decomp Temp:Decomp Text:NOT KNOWN
Vapor Pres:NOT KNOWN
Vapor Density:NOT KNOWN
Spec Gravity:SEE SUPP DATA
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SEWN CLOTH BAGS CONTAINING PROPELLENT.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
ACIDS AND BASES.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS.
Hazardous Decomposition Products:COMBUSTION:CO*2,CO,NITROGEN
OXIDES,AMMONIA.POSS LEAD FUMES/OXIDES,METHANE,ALDEHYDES,CARBOXYLIC
ACIDS & HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISP MUST BE IAW FED,STATE,& LOC REGS.COORDINATE
W/ SUPPORTING INSTALLATION/MACOM ENVIRON OFFICE PRIOR TO DISP
.EMPTY CONTR RETAINS RESIDUES.OBSERVE ALL HAZARD PRECAUTIONS.USE
EMPTY CONTAINER ON LY FOR STORAGE AND SHIPMENT OF ORIGINALPRODUCT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.